Structural and chemical composition of biochar
Structural composition Thermal degradation of cellulose between 250ºC and 350ºC results in considerable mass loss in the form of volatiles, leaving behind a rigid amorphous C matrix. As the pyrolysis temperature increases, so thus the proportion of aromatic carbon in the biochar, due to the relative increase in the loss of volatile matter (initially water, followed by hydrocarbons, tarry vapors, H2, CO and CO2), and the conversion of alkyl and O-alkyl C to aryl C (Baldock and Smernik, 2002; Demirbas, 2004). Source: http://venice.umwblogs.org/exhibit/the-conservation-of-venetian-building-materials/wood/ Around 330ºC, polyaromatic graphene sheets begin to grow laterally, at the expense of the amorphous C phase, and eventually coalesce. Above 600ºC, carbonization becomes the dominant process. Carbonization is marked by the removal of most remaining non-C atoms and consequent relative increase of the C content, which can be up to 90% (by w...
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